block: convert is_sync helpers to use REQ_OPs.

This patch converts the is_sync helpers to use separate variables
for the operation and flags.

Signed-off-by: Mike Christie <mchristi@redhat.com>
Reviewed-by: Christoph Hellwig <hch@lst.de>
Reviewed-by: Hannes Reinecke <hare@suse.com>
Signed-off-by: Jens Axboe <axboe@fb.com>